Cracow University of Technology

Physical Organic Chemistry and Organocatalysis
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Publications
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2019
Understanding the molecular mechanism rearrangement of internal nitronic ester into nitronorbornene in the light of MEDT study
Kącka-Zych A.
Molecules, 24, 462 (2019)
New rigid polycyclic bis(phosphane) for asymmetric catalysis
Pietrusiewicz K.M., Szwaczko K., Mirosław B., Dybala I., Jasiński R., Demchuk O.M.
Molecules, 24, 571 (2019)
Experimental and Computational Studies on Stepwise [3+2]-Cycloadditions of Diaryldiazomethanes with Electron-Deficient Dimethyl (E)- and (Z)-2,3-Butenedioates
Mlostoń G., Celeda M., Jasiński R., Heimgartner H.
European Journal of Organic Chemistry, 422-431 (2019)
Unexpected molecular mechanism of trimethylsilyl bromide elimination from 2-(trimethylsilyloxy)-3-bromo-3-methyl-isoxazolidines
Kącka-Zych A., Jasiński R.
Theoretical Chemistry Accounts, 138, 81 (2019)
A Molecular Electron Density Theory study of the Lewis acid – catalyzed decomposition reaction of nitroethyl benzoate using aluminium derivatives
Kącka-Zych A., Ríos-Gutiérrez M., Domingo L.R.
Journal of Physical Organic Chemistry, 32, e3938 (2019)
The structural aspects of the transformation of 3-nitroisoxazoline-2-oxide to 1-aza-2,8-dioxabicyclo[3.3.0]octane derivatives: experimental and MEDT theoretical study
Woliński P., Kącka-Zych A., Dziuk B., Ejsmont K., Łapczuk-Krygier A., Dresler E.
Journal of Molecular Structure, 1192, 27-34 (2019)
Understanding of the molecular mechanism of the phenylsulfenic acid elimination from nitroalkyl systems
Jasiński R.
Journal of Molecular Graphics and Modelling, 89, 109 (2019)
Competition between [2+1]- and [4+1]-cycloaddition mechanisms in reactions of conjugated nitroalkenes with dichlorocarbene in the light of DFT computational study
Alnajjar R.A., Jasiński R.
Journal of Molecular Modeling, 25 157 (2019)
A general phenomenon of spontaneous amplification of optical purity under an achiral chromatographic conditions
Pietrusiewicz K.M., Borkowski M., Strzelecka D., Kielar K., Kicińska W., Karevych S. , Jasiński R., Demchuk O.M.
Symmetry, 11 680 (2019)
Microwave-Assisted Solvent-Free Synthesis of Ipsapirone
Kulaga D., Jaskowska J., Jasiński R
Journal of Heterocyclic Chemistry, 56, 1498 (2019)
Novel Functionalized beta-Nitrostyrenes: Promising Candidates for New Antibacterial Drugs
Boguszewska-Czubara A., Kula K., Wnorowski A., Biernasiuk A., Popiolek P., Miodowski D., Demchuk O.M., Jasiński R
Saudi Pharmaceutical Journal, 27, 593-601 (2019)
Recent progress in the field of cycloaddition reactions involving conjugated nitroalkenes
Łapczuk-Krygier A., Kącka-Zych A., Kula K.
Current Chemistry Letters, 8, 13-38 (2019)
2018
B-Trifluoromethylated nitroethenes in Diels-Alder reaction with cyclopentadiene: A DFT computational study
Jasiński R.
Journal of Fluorine Chemistry, 206, 1-7 (2018)
The influence of Lewis acid catalyst on the kinetic and molecular mechanism of nitrous acid extrusion from 3-phenyl-5-nitro-2-isoxazoline: DFT computational study
Lapczuk-Krygier A., Jaskowska J., Jasiński R.
Chemistry of Heterocyclic Compounds, 54, 1172-1174 (2018)
Regiospecific formation of the nitromethyl-substituted 3-phenyl-4,5-dihydroisoxazole via [3+2] cycloaddition
Mirosław B., Babyuk D., Łapczuk-Krygier A., Kącka A., Demchuk O., Jasiński R.,
Monatshefte für Chemie - Chemical Monthly, 149, 1877-1884 (2018)
Green in water sonochemical synthesis of tetrazolopyrimidine derivatives by a novel core-shell magnetic nanostructure catalyst
Maleki A., Rahimi J., Demchuk O.M., Wilczewska A.Z., Jasiński R.
Ultrasonics Sonochemistry, 43, 262-271 (2018)
Regioselectivity, stereoselectivity and molecular mechanism of [3+2] cycloaddition reactions between 2-methyl-1-nitroprop-1-ene and (Z)-C-aryl-N-phenylnitrones in the light of DFT computational study
Dresler E., Kącka-Zych A., Kwiatkowska M., Jasiński R.,
Journal of Molecular Modeling, 24, 329 (2018)
Competition between one-step and two-step mechanism in polar [3+2] cycloadditions of (Z)-C-(3,4,5-trimethoxyphenyl)-N-methyl-nitrone with (Z)-2-EWG-1-bromo-1-nitroethenes
Jasiński R.
Computational and Theoretical Chemistry, 1125, 77-85 (2018)
A clean and simple method for deprotection of phosphines from borane complexes
Demchuk O.M., Jasiński R., Strzelecka D., Dziuba K., Kula K., Chrzanowski J., Krasowska D.
Pure and Applied Chemistry, 90, 49-62 (2018)
Does a fluorinated Lewis acid catalyst change the molecular mechanism of the decomposition process of nitroethyl carboxylates?
Kącka-Zych A., Domingo L.R., Jasiński R.
Research on Chemical Intermediates, 44, 325-337 (2018)
A DFT computational study on the [3+2] cycloaddition between parent thionitrone and nitroethene
Kula K., Łapczuk-Krygier A.,
Current Chemistry Letters, 7, 27-34 (2018)
2017
A DFT computational study on molecular mechanism of [3+2] cycloaddition reactions between nitroethene and benzonitrile N-oxides
Jasiński R., Jasińska E., Dresler E.
Journal of Molecular Modeling, 23, 13 (2017)
One-step versus two-step mechanism of Diels-Alder reaction of 1-chloro-1-nitroethene with cyclopentadiene and furan
Jasiński R.
Journal of Molecular Graphics and Modelling 75, 55-61 (2017)
Understanding the mechanism of the decomposition reaction of nitroethyl benzoate through the Molecular Electron Density Theory
Kącka-Zych A., Domingo L.R., Ríos-Gutiérrez M., Jasiński R.
Theoretical Chemistry Accounts, 136, 129 (2017)
Unexpected course of reaction between (E)-2-aryl-1-cyano-1-nitroethenes and diazafluorene: why is there no 1,3-dipolar cycloaddition?
Jasiński R., Kula K., Kącka A., Mirosław B.
Monatshefte für Chemie - Chemical Monthly, 148, 909-915 (2017)
A full regio- and stereoselective synthesis of 4-nitroisoxazolidines via stepwise [3+2] cycloaddition reactions between (Z)-C-(9-anthryl)-N-arylnitrones and (E)-3,3,3-trichloro-1-nitroprop-1-ene: comprehensive experimental and theoretical study
Jasiński R., Zmigrodzka M., Dresler E., Kula K.
Journal of Heterocyclic Chemistry, 54, 3314-3320 (2017)
A DFT computational study on the molecular mechanism of reaction between pyridinium salts and pi-deficient ethylenes: why furan derivatives are formed instead of feasible cyclopropane derivatives and/or [3+2] cycloadducts?
Emamian S., Jasiński R.
Computational and Theoretical Chemistry 1114, 87-100 (2017)
A dramatic change of kinetic conditions and molecular mechanism of decomposition processes of nitroalkyl carboxylates catalyzed by ethylammonium cations
Kącka A., Jasiński R.
Computational and Theoretical Chemistry, 1104, 37-42 (2017)
A unique example of non-catalyzed [3+2] cycloaddition involving (2E)-3-aryl-2-nitroprop-2-enenitriles
Zmigrodzka M., Dresler E., Hordyjewicz-Baran Z., Kulesza R., Jasiński R.
Chemistry of Heterocyclic Compounds, 53, 1161-1162 (2017)
Triethylsulfonium and triethylphosphonium cations as novel catalysts for the decomposition process of nitroethyl benzoates
Kącka A., Jasiński R.
Phosphorus Sulfur and Silicon and the Related Elements, 192, 1252-1258 (2017)
A quantum-chemical DFT approach to elucidation of the chirality transfer mechanism of the enantioselective Suzuki–Miyaura cross-coupling reaction
Jasiński R., Demchuk O.M., Babyuk D.
Journal of Chemistry, 3617527 (2017)
DFT study of the decomposition reactions of nitroethyl benzoates catalyzed by the 1,3-dimethylimidazolium cation
Kącka A., Jasiński R.
Current Chemistry Letters, 6, 15-22 (2017)
2016
First example of stepwise, zwitterionic mechanism for bicyclo[2.2.1]hept-5-ene (norbornene) formation process catalyzed by the 1-butyl-3-methylimidazolium cations
Jasiński R.
Monatshefte für Chemie - Chemical Monthly, 147, 1207-1213 (2016)
In the search for experimental and quantumchemical evidence for zwitterionic nature of (2E)-3-[4-(dimethylamino)phenyl]-2-nitroprop-2-enenitrile - an extreme example of donor-p-acceptor push-pull molecule
Jasiński R., Mirosław B., Demchuk O.M., Babyuk D., Łapczuk-Krygier A.
Journal of Molecular Structure, 1108, 689-697 (2016)
A DFT mechanistic study of thermal decomposition reactions of nitroethyl carboxylates: undermine of “pericyclic” insight
Kącka A., Jasiński R.
Heteroatom Chemistry, 27, 279-289 (2016)
A reexamination of molecular mechanism of Diels-Alder reaction between tetrafluoroethene and cyclopentadiene
Jasiński R.
Reaction Kinetics, Mechanisms and Catalysis, 119, 49-57 (2016)
Novel synthesis scheme and in vitro antimicrobial evaluation of a panel of (E)-2-aryl-1-cyano-1-nitroethenes
Boguszewska-Czubara A, Łapczuk-Krygier A., Rykała K., Biernasiuk A., Wnorowski A, Popiołek Ł., Maziarka A., Hordyjewska A., Jasiński R.
Journal of Enzyme Inhibition and Medicinal Chemistry, 31, 900-907 (2016)
Experimental and theoretical DFT study on synthesis of sterically crowded 2,3,3,(4)5-tetrasubstituted-4-nitroisoxazolidines via 1,3-dipolar cycloaddition reactions between ketonitrones and conjugated nitroalkenes
Jasiński R., Mróz K., Kącka A.
Journal of Heterocyclic Chemistry, 53, 1424-1429 (2016)
Utilisation of chiral phosphorus ligands in atroposelective cross-coupling reactions
Demchuk O.M., Kaplon K., Kącka A., Pietrusiewicz K.M
Phosphorus Sulfur and Silicon and the Related Elements, 191, 180-200 (2016)
Organophosphorus ligands: recent developments in design, synthesis and application in environmentally benign catalysis
Demchuk O.M., Jasiński R.
Phosphorus Sulfur and Silicon and the Related Elements, 191, 245-253 (2016)
A desulfonylation process as easy route for synthesis of 1,4-dinitro-1,3-dienes: mechanistic study
Jasiński R., Dresler E.
Phosphorus Sulfur and Silicon and the Related Elements, 191, 311-315 (2016)
[3+2] Cycloadditions of 1-halo-1-nitroethenes with (Z)-C-(3,4,5-trimethoxyphenyl)-N-methyl-nitrone as regio- and stereocontrolled source of novel bioactive compounds: preliminary studies
Jasiński R., Dresler E., Mikulska M., Polewski D.
Current Chemistry Letters, 5, 123-128 (2016)
The halogenless catalytic transition metal mediated cross-coupling reactions. A sustainable alternative for utilisation of organohalides
Demchuk O.M., Jasiński R., Formela A.
in.: Chemistry Beyond Chlorine, (Eds. Tundo P., He L-N., de Araujo Mota C.J., Lokteva E.) ISBN 978-3-319-30073-3, Springer (2016)
2015
In the searching for zwitterionic intermediates on reaction paths of [3+2] cycloaddition reactions between 2,2,4,4-tetramethyl-3-thiocyclobutanone S-methylide and polymerizable olefins
Jasiński R.
RSC Advances, 5, 101045-101048 (2015)
A new mechanistic insight on beta-lactam systems formation from 5-nitroisoxazolidines
Jasiński R.
RSC Advances, 5, 50070-50072 (2015)
A polar nature of benzoic acids extrusion from nitroalkyl benzoates: DFT mechanistic study
Jasiński R., Kącka A.
Journal of Molecular Modeling, 21, 59 (2015)
A stepwise, zwitterionic mechanism for the 1,3-dipolar cycloaddition between (Z)-C-4-methoxyphenyl-N-phenylnitrone and gem-chloronitroethene catalyzed by 1-butyl-3-methylimidazolium ionic liquid cations
Jasiński R.
Tetrahedron Letters, 56, 532-535 (2015)
On the question of zwitterionic intermediates in 1,3-dipolar cycloadditions between hexafluoroacetone and sterically crowded diazocompounds
Jasiński R.
Journal of Fluorine Chemistry, 176, 35-39 (2015)
New insights into the mechanism of reduction of tertiary phosphine oxides by means of phenylsilane
Demchuk O.M., Jasiński R., Pietrusiewicz K.M.
Heteroatom Chemistry, 26, 441-448 (2015)
Kinetic aspects of [3+2] cycloaddition reactions between (E)-3,3,3-trichloro-1-nitroprop-1-ene and ketonitrones
Jasiński R., Mróz K.
Reaction Kinetics, Mechanisms and Catalysis, 116, 35-41 (2015)
Nitroacetylene as dipolarophile in [2 + 3] cycloaddition reactions with allenyl-type three-atom components: DFT computational study
Jasiński R.
Monatshefte für Chemie - Chemical Monthly, 146, 591-599 (2015)
Nitroallylic systems in [2+3] cycloaddition reactions with nitrones: a DFT computational study
Jasiński R.
Journal of Heterocyclic Chemistry, 52, 185-192 (2015)
Single crystal X-ray structure of (Z)-1-bromo-1-nitro-2-phenylethene
Łapczuk-Krygier A., Ponikiewski Ł.
Current Chemistry Letters, 4, 21-26 (2015)
An experimental and quantumchemical study of [2+3] cycloaddition between (Z)-C-(m,m,p-trimethoxyphenyl)-N-(p-methyphenyl)-nitrone and (E)-3,3,3-trichloro-1-nitroprop-1-ene: mechanistic aspects
Szczepanek A., Jasińska E., Kącka A., Jasiński R.
Current Chemistry Letters, 4, 33-44 (2015)
2014
Molecular mechanism of thermal decomposition of fluoronitroazoxy compounds: DFT computational study
Jasiński R.
Journal of Fluorine Chemistry, 160, 29-33 (2014)
A DFT computational study on the molecular mechanism of the nitro group migration in the product derived from 3-nitro-2-(trifluoromethyl)-2H-chromene and 2-(1-phenylpropylidene)malononitrile
Łapczuk-Krygier A., Korotaev V.Yu., Barkov A.Yu., Sosnovskikh V.Yu., Jasińska E., Jasiński R.
Journal of Fluorine Chemistry, 168, 236-239 (2014)
Searching for zwitterionic intermediates in Hetero Diels-Alder reactions between methyl a,p-dinitrocinnamate and vinyl-alkyl ethers
Jasiński R.
Computational and Theoretical Chemistry, 1046, 93-98 (2014)
An experimental and theoretical study of the hetero Diels-Alder reactions between (E)-2-aryl-1-cyano-1-nitroethenes and ethyl vinyl ether: one-step or zwitterionic, two-step mechanism?
Jasiński R., Kubik M., Łapczuk-Krygier A., Kącka A., Dresler E., Boguszewska-Czubara A.
Reaction Kinetics, Mechanisms and Catalysis, 113, 333-345 (2014)
2-Methoxynaphthylnaphthoquinone and its solvate: synthesis and structure - properties relationship
Demchuk O.M., Justyniak I., Mirosław B., Jasiński R.
Journal of Physical Organic Chemistry, 27, 66-73 (2014)
Regio- and stereoselectivity of polar [2+3] cycloaddition reactions between (Z)-C-(3,4,5-trimethoxyphenyl)-N-methylnitrone and selected (E)-2-substituted nitroethenes
Jasiński R., Ziółkowska M. Demchuk O.M., Maziarka A.
Central European Journal of Chemistry, 12, 586-593 (2014)
The crystal structure of (1RS,4RS,5RS,6SR)-5-cyano-5-nitro-6-phenyl-bicyclo[2.2.1]hept-2-ene
Łapczuk-Krygier A., Ponikiewski Ł., Jasiński R.
Crystallography Reports, 59, 961-963 (2014)
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